Introduction: The Challenge of Oily Wastewater
In oil and water treatment operations, one problem consistently ranks among the most difficult to solve: oil that refuses to separate from water.
Whether it is produced water from oil extraction, polymer-containing wastewater from enhanced oil recovery, or oily effluent from industrial processes, the challenge is the same. Free oil rises and can be skimmed. Dispersed oil can be captured by coalescing media. But emulsified oil — tiny droplets stabilized by surfactants, fine solids, and interfacial films — remains stubbornly suspended, resisting gravity separation and passing through conventional treatment equipment.
This is where the Water Clarifier (Deoiler) comes in.
A Water Clarifier — also called a reverse demulsifier or deoiler — is a chemical agent specifically designed to break oil-in-water emulsions, allowing oil droplets to coalesce, rise, and be separated from the water phase. It is the chemical counterpart to physical separation equipment, and it plays a critical role in produced water treatment, wastewater purification, and oil recovery.
What Is a Water Clarifier (Deoiler)?
A Water Clarifier (Deoiler) is a reverse-phase demulsifier used to treat oilfield produced water and polymer-containing wastewater. Unlike conventional demulsifiers — which break water-in-oil emulsions in crude oil — reverse demulsifiers target oil-in-water emulsions, where oil is the dispersed phase and water is the continuous phase.
The product works by:
- Neutralizing interfacial charges
— oil droplets in water often carry negative surface charges that prevent coalescence. The deoiler neutralizes these charges.
- Displacing stabilizing agents
— surfactants, fine solids, and polymers that stabilize the emulsion are displaced from the oil-water interface.
— once the interfacial film is weakened, oil droplets merge into larger droplets that can rise by gravity.
- Clarifying the water phase
— the treated water becomes clear, meeting discharge or reinjection standards.
The result is effective oil-water separation, purified sewage, and improved recovery of oil products.
Technical Specifications
No. | Item | Indicator |
1 | Appearance | Homogeneous liquid |
2 | pH | 3–9 |
3 | Water solubility | Miscible with water, no stratification |
4 | Condensation point, °C | ≤−10 |
5 | Degreasing rate | Meet on-site requirements |
Note: Specifications can be customized according to your specific wastewater characteristics.
How It Works in Practice
Step 1: Injection
The Water Clarifier is dosed into the wastewater stream — typically at the inlet of a separation vessel, flotation unit, or filtration system. It can be injected continuously via metering pump or added in batch mode.
Step 2: Reaction
The deoiler molecules rapidly disperse through the water phase and migrate to the oil-water interface. Within seconds to minutes, they begin destabilizing the emulsion.
Step 3: Coalescence
Destabilized oil droplets collide and merge. Small droplets become larger droplets. The larger the droplet, the faster it rises.
Step 4: Separation
The coalesced oil rises to the surface, where it can be skimmed or decanted. The clarified water phase exits the system, ready for discharge, reinjection, or further treatment.
Step 5: Oil Recovery
The separated oil is recovered and can be returned to the process stream, improving overall oil recovery and reducing waste.
Main Applications
1. Oilfield Produced Water Treatment
Produced water is the largest byproduct stream in oil and gas production. The U.S. alone generates over 24 billion barrels annually. Produced water contains dispersed and emulsified oil that must be removed before the water can be reinjected or discharged. The Water Clarifier (Deoiler) is used at the primary separation stage to break oil-in-water emulsions and enhance oil removal efficiency.
2. Polymer-Containing Wastewater
Enhanced oil recovery (EOR) using polymer flooding generates produced water containing residual polyacrylamide. These polymers stabilize oil-in-water emulsions, making separation extremely difficult. Conventional treatments often fail. The Water Clarifier is specifically formulated to work in polymer-containing wastewater, breaking emulsions that other chemicals cannot.
3. Industrial Oily Wastewater
Beyond oilfield applications, the Water Clarifier is used for:
- Refinery wastewater treatment
- Petrochemical oily effluent
- Steel and metal processing wastewater
- Food processing oily wastewater
- Bilge water treatment
4. Oil Recovery Enhancement
By breaking emulsions and allowing oil to separate, the Water Clarifier helps recover oil that would otherwise be lost in the water phase. This improves overall oil recovery and reduces the environmental impact of oily wastewater discharge.
Equipment and Chemical Synergy
The Water Clarifier (Deoiler) is designed to work alongside physical separation equipment for optimal results:
Treatment Stage | Equipment | Chemical | Function |
Primary separation | Tank-in-Tank, CPI | Demulsifier | Remove free oil and break loose emulsions |
Fine separation | ZJYS Fine Oil-Water Separator, DAF | Water Clarifier (Deoiler) | Break stable oil-in-water emulsions |
Polishing | Filtration units | — | Remove residual oil and suspended solids |
Water conditioning | — | Corrosion inhibitor, Biocide, Scale inhibitor | Protect downstream equipment |
The Water Clarifier is most effective when used upstream of fine separation equipment. By breaking the emulsion and promoting coalescence, it allows the physical separator to capture oil droplets that would otherwise pass through.
Comparison: Water Clarifier vs. Conventional Treatment
Factor | Conventional Treatment | With Water Clarifier |
Emulsified oil removal | Poor — passes through | High — emulsion broken |
Polymer-containing water | Very difficult | Effective |
Water clarity | Cloudy, oil sheen | Clear, no sheen |
Oil recovery | Low | High |
Chemical dosage | Higher | Lower |
Equipment performance | Reduced by stable emulsions | Optimized |
Compliance | Risk of exceedance | Consistent compliance |
Packaging and Customization
Standard packaging:
- 200L drums
- 1000L IBC tanks
- Custom packaging available upon request
Customization:
The Water Clarifier formulation can be tailored to your specific wastewater characteristics, including salinity, polymer content, oil type, and operating temperature. Please provide your water analysis for a tailored recommendation.
Why Choose Jusen Chem?
Products supplied to major oilfields and industrial customers worldwide
- Effective on stable emulsions:
Works where conventional chemicals fail
Designed for EOR produced water
Works with our separation equipment for complete treatment
Formulations tailored to your water chemistry
Stable supply and factory-direct pricing
Efficient logistics from China to global markets
Our team can recommend dosage and application methods
FAQ
Q1: What is a Water Clarifier (Deoiler)?
It is a reverse demulsifier used to break oil-in-water emulsions in produced water and oily wastewater. It separates oil from water, clarifies the water phase, and improves oil recovery.
Q2: How is it different from a regular demulsifier?
A regular demulsifier breaks water-in-oil emulsions (water droplets in oil). A Water Clarifier breaks oil-in-water emulsions (oil droplets in water). They target opposite emulsion types.
Q3: Can it treat polymer-containing wastewater?
Yes. The Water Clarifier is specifically formulated to work in polymer-containing wastewater from EOR operations, where conventional treatments often fail.
Q4: What is the recommended dosage?
Dosage depends on the oil content, emulsion stability, and water chemistry. Typical dosage ranges from 10–100 mg/L. Our technical team can recommend specific dosage based on your water analysis.
Q5: How should it be applied?
It is typically injected continuously via metering pump at the inlet of a separation vessel, flotation unit, or filtration system. Batch treatment is also possible for smaller volumes.
Q6: What is the packaging?
Standard packaging is 200L drums or 1000L IBC tanks. Custom packaging is available upon request.
Q7: Can you provide samples?
Yes, samples can be provided for evaluation. Please contact us with your water analysis and treatment requirements.
Contact Us
For quotations, technical data sheets, or samples of Water Clarifier (Deoiler), please contact us:
📧 Email: info@jusenchem.com
📞 WhatsApp: +86 18954690080
Jusen Chem — your reliable partner for oil and water treatment chemicals and equipment.